Search results for " pyrene"
showing 10 items of 13 documents
Effects of glaciation on karst hydrology and sedimentology during the Last Glacial Cycle: The case of Granito cave, Central Pyrenees (Spain)
2021
In Alpine regions, speleothem development on karst systems largely occurs during warm interglacial or interstadial phases due to their limited growth during cold stages. Still, recent attention has been given to the role of clastic sediments in caves, less dependent on temperature conditions. Yet, only a small number of caves worldwide preserve both speleothems and detrital deposits. Here we present an outstanding record of fine-grain laminated sediments and carbonate speleothems from the Granito cave (South Central Pyrenees, Spain) associated with seasonal to annual hydroclimatic pulses through the Last Glacial Cycle (LGC). Analysis of cave clastic facies together with new absolute dates o…
Synthesis and characterization of perfluoroalkyl-pyrenes embedded in a polymethylmethacrylate matrix
2012
Fosildiagénesis del anélido Rotularia spirulaea (Lamarck, 1818) (Polychaeta, Serpulidae) en el Eoceno del dominio pirenaico occidental
2018
The presence of the fossil polychaete Rotularia spirulaea (Lamarck, 1818) in Eocene deposits (middle Lutecian – upper Bartonian and (?) Priabonian) belonging to the western Pyrenean Domain is verified. In this paper, a fossildiagenetic study has been carried out. Fossils from three areas, corresponding to diff erent depositional settings, have been analysed. In area 1, sediments of the Ardanatz Sandstone and Ilundain Marls formations [Pamplona Basin and adjoining areas (Navarre)], were sampled. Here, the specimens of R. spirulaea were not substantially affected by taphonomic reworking and the original microstructure of the carbonate tube is preserved. The test consists of a thick external …
Mechanisms involved in lipid accumulation and apoptosis induced by 1-nitropyrene in Hepa1c1c7 cells
2011
International audience; 1-Nitropyrene (1-NP) is a nitro-polycyclic aromatic hydrocarbon (nitro-PAH) present in diesel exhaust and bound to particular matter in urban air. We show that 1-NP and the referent PAH benzo(a)pyrene (BP) induce apoptosis and a lipid accumulation dependent on cytochrome P450 1A1-metabolites in mouse hepatoma cells, whereas 1-amino-pyrene had no effect. The caspase inhibitor, N-benzyloxycarbonyl-Val-Ala-Asp(O-Me) fluoromethyl ketone (Z-VAD-fmk), inhibits 1-NP-induced apoptosis, but failed to alter 1-NP-triggered lipid accumulation determined by Nile red staining. We further show that cholesterol and fatty acid contents are modified after nitro-PAH exposure and that 1…
Thiophene pyrenyl derivatives for the supramolecular processability of single-walled carbon nanotubes in thin film heterojunction
2017
Abstract A major problem for the use of single-wall carbon nanotubes (SWCNTs) in electronic devices relates to their poor processability. Chemical modification inevitably introduces defects in the nanotube lattice, resulting in a loss of electronic properties. In this contest, we report on a supramolecular approach with the aim of increasing the dispersion of SWCNTs in solution and in organic semiconductor matrices by ensuring the optoelectronic properties. In particular, new pyrenyl derivatives of thiophene have been synthesized and used to improve the solubility of SWCNTs for electron transfer in thin film heterojunction with poly(3-hexylthiophene) (P3HT) as donor system. Photoinduced ele…
Alkyloxy modified pyrene fluorophores with tunable photophysical and crystalline properties
2019
Novel alkyloxy modified 2,7-di-tert-butyl-4,5,9,10-tetra(arylethynyl)pyrenes were prepared through a straightforward Sonogashira coupling approach. Optical properties such as quantum yields and absorption/emission spectra of the fluorophores were investigated by UV/Vis and fluorescence measurements. Aggregation induced excimer formation of the chromophores in polar solvents and in the solid state was proved by the presence of a characteristic bathochromically shifted emission band and a decrease of the emission capability. These results strongly indicate the unexpected observation that the excimer formation of adjacent pyrene rings is not prevented by the introduction of bulky tert-butyl su…
Microgastrinae (Hymenoptera: Braconidae) in the Forest State of Artikutza (Navarra: Spain): Diversity and Community Structure
2013
Microgastrinae is one of the largest subfamilies of the Braconidae with about 2,000 described species worldwide. These wasps are of enormous ecological interest due to their role in controlling the caterpillar populations. This study analyses diversity and community structure within the Microgastrinae in the Artikutza Forest, located in the Peñas de Aia Natural Park, western Pyrenees, Spain. The specimens were collected in two different habitats: mixed forest and beech forest. A total of 524 specimens, belonging to nine separate genera and 27 species were captured. Alpha, beta and gamma diversity were analyzed. Additionally, the relationship between Microgastrinae phenology and climatic con…
Kinematics, deformation partitioning and late Variscan magmatism in the Agly massif, Eastern Pyrenees, France
2020
International audience; In order to constrain the finite deformation pattern of the Variscan basement of the Agly massif, a detailed structural analysis over the whole Agly massif was performed. Our investigation combined geological mapping, reappraisal of published and unpublished data completed with our own structural work. Results are provided in the form of new tectonic maps and series of regional cross-sections through the Agly massif. At variance from previous studies, we identified three deformation fabrics named D1, D2 and D3. The D1 deformation is only relictual and characterized by a broadly northwest-southeast striking and eastward dipping foliation without any clear mineral and …
CCDC 1965274: Experimental Crystal Structure Determination
2020
Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B
CCDC 1532006: Experimental Crystal Structure Determination
2017
Related Article: P. J. Llabres-Campaner, J. Pitarch-Jarque, R. Ballesteros-Garrido, B. Abarca, R. Ballesteros, E. García-España|2017|Dalton Trans.|46|7397|doi:10.1039/C7DT00855D